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Strontium ion-selective electrodes based on the diamides with pyridine ring as ionophores | |
Qian, GY; Wu, MB; Wu, GL; Huang, S; Yan, YK; Tian, BZ | |
1998-12-01 | |
发表期刊 | TALANTA
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卷号 | 47期号:5页码:1149-1155 |
关键词 | Strontium Ion-selective Electrode Diamide Ionophore |
摘要 | Poly(vinyl chloride) membrane strontium ion-selective electrodes were developed by using three lipophilic diamides containing pyridine ring as ionophores. The relationship between the structure of the ionophores and the performance of these electrodes, as well as the effects of the plasticizers and additives, were investigated. The Sr2+-electrode based on N,N,N',N'-tetracyclohexyl-2,6-pyridine-bis(methyleneoxy acetamide) as neutral carrier, potassium tetrakis (p-chlorophenyl) borate (KTpClPB) as additive, and o-nitrophenyloctyl ether (o-NPOE) as plasticizing solvent. It exhibits excellent properties with a Nernstian slope of 29 mV/pSr(2+) and a linearity range or 2 x 10(-5) to 1 x 10(-2) M at 25 degrees C, K-Sr,Ba(Pot) = 2 x 10(-2). (C) 1998 Elsevier Science B.V. All rights reserved. |
语种 | 英语 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/6010 |
专题 | 青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | 1.Chinese Acad Sci, Inst Salt Lake, Xining 810008, Peoples R China 2.Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China |
推荐引用方式 GB/T 7714 | Qian, GY,Wu, MB,Wu, GL,et al. Strontium ion-selective electrodes based on the diamides with pyridine ring as ionophores[J]. TALANTA,1998,47(5):1149-1155. |
APA | Qian, GY,Wu, MB,Wu, GL,Huang, S,Yan, YK,&Tian, BZ.(1998).Strontium ion-selective electrodes based on the diamides with pyridine ring as ionophores.TALANTA,47(5),1149-1155. |
MLA | Qian, GY,et al."Strontium ion-selective electrodes based on the diamides with pyridine ring as ionophores".TALANTA 47.5(1998):1149-1155. |
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