Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K

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	Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K
	Deng, Tianlong 1; Li, Dan
	2008-11-01
发表期刊	JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号	53 期号:11 页码:2488-2492
摘要	The solubility and the physicochemical properties (densities, viscosities, refractive indices, conductivities, and pH) of the liquid-solid metastable system (NaCl + LiCl + CaCl2 + H2O) at 288.15 K have been studied using the isothermal evaporation method. On the basis of the experimental data, the dry-salt phase diagram, water phase diagram, and the diagram of physicochemical properties versus composition in the system were plotted. The dry-salt phase diagram of the system includes two three-salt cosaturated points of (CaCl2 center dot 6H(2)O + NaCl + CaCl2 center dot LiCl center dot 5H(2)O) and (LiCl center dot H2O + NaCl + CaCl2 center dot LiCl center dot 5H(2)O), five metastable solubility isotherm curves, and four crystallization regions corresponding to sodium chloride (NaCl), lithium chloride monohydrate (LiCl center dot H2O), calcium chloride hexahydrate (CaCl2 center dot 6H(2)O), and the double salt LiCl center dot CaCl2 center dot 5H(2)O. No solid solution was found. It was found that the physicochemical properties in the metastable equilibrium solution change regularly with increasing CaCl2 concentration.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5863
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Chengdu Univ Technol, Coll Mat Chem & Chem Engn, Chengdu 610059, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式 GB/T 7714	Deng, Tianlong,Li, Dan. Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2008,53(11):2488-2492.
APA	Deng, Tianlong,&Li, Dan.(2008).Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,53(11),2488-2492.
MLA	Deng, Tianlong,et al."Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 53.11(2008):2488-2492.