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Research on the Carbothermic Reduction Procedure of SrSO4 with Carbon
Chen, Si-ming; Duan, Dong-ping; Zou, Xing-wu
2019
发表期刊RARE METAL TECHNOLOGY 2019
ISSN2367-1181
页码201-211
摘要Carbothermic reduction of celestite is the first procedure of universal process for preparing SrCO3. However, only one species as SrS without SrO can be found in reduction product of SrSO4 by solid carbon at the reduction temperature below 1273 K, and less effect of factors such as C/O ratio and reaction temperature on the reduction of SrSO4 is found. An investigation on reduction of SrSO4 is carried out. The experiment result reveals that the reduction of SrSO4 is a reduction-decomposition process: SrSO4 is first reduced to SrSO3, and then, the SrSO3 was decomposed into SrSO4 and SrS below 1273 K or SrO and SO2 above 1273 K. Kinetic analysis of the reduction of SrSO4 reveals that the reduction of SrSO4 is controlled by step of interface reaction, and its activation energy is 105.4 kJ/mol.
DOI10.1007/978-3-030-05740-4_20
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/34047
专题盐湖资源综合利用工程技术中心
中国科学院青海盐湖研究所
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GB/T 7714
Chen, Si-ming,Duan, Dong-ping,Zou, Xing-wu. Research on the Carbothermic Reduction Procedure of SrSO4 with Carbon[J]. RARE METAL TECHNOLOGY 2019,2019:201-211.
APA Chen, Si-ming,Duan, Dong-ping,&Zou, Xing-wu.(2019).Research on the Carbothermic Reduction Procedure of SrSO4 with Carbon.RARE METAL TECHNOLOGY 2019,201-211.
MLA Chen, Si-ming,et al."Research on the Carbothermic Reduction Procedure of SrSO4 with Carbon".RARE METAL TECHNOLOGY 2019 (2019):201-211.
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