Coordination polymers of lanthanides incorporating N,N '-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystal structures

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	Coordination polymers of lanthanides incorporating N,N '-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystal structures
	Chen, Wenqian 1; Chen, Yanmei 1; Liu, Wei 1; Lei, Tao 2; Gao, Qian 1; Kim, Damin 3; Su, David 3; Li, Wu 2; Li, Yahong 1
	2012
发表期刊	JOURNAL OF COORDINATION CHEMISTRY
卷号	65 期号:24 页码:4430-4440
关键词	Schiff-base Phthalen-ol Lanthanide Complexes Crystal Structure
摘要	Reaction of Ln(NO3)3?.?6H2O with H2napn (H2napn?=?N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn)(SCN)(C2H5OH)2(NO3)2] n (1), [La(H2napn)2(SCN)(NO3)2] n (2), and [Ln(H2napn)1.5(NO3)3] n [Ln?=?La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (27) with lanthanides. Each metal center of 17 is nine-coordinate. Lanthanide contraction is observed in 37.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5579
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Key Lab Salt Lake Resources & Chem, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada
推荐引用方式 GB/T 7714	Chen, Wenqian,Chen, Yanmei,Liu, Wei,et al. Coordination polymers of lanthanides incorporating N,N '-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystal structures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(24):4430-4440.
APA	Chen, Wenqian.,Chen, Yanmei.,Liu, Wei.,Lei, Tao.,Gao, Qian.,...&Li, Yahong.(2012).Coordination polymers of lanthanides incorporating N,N '-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystal structures.JOURNAL OF COORDINATION CHEMISTRY,65(24),4430-4440.
MLA	Chen, Wenqian,et al."Coordination polymers of lanthanides incorporating N,N '-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystal structures".JOURNAL OF COORDINATION CHEMISTRY 65.24(2012):4430-4440.