Extraction kinetics of rubidium in brine solutions by 4-tert-butyl-2-(alpha-methylbenzyl)phenol sulfonated kerosene using a single drop method | |
Huang, Dongfang; Zheng, Hong; Li, Bo; Ma, Guixiang | |
第一作者 | Huang, Dongfang |
2018-12 | |
发表期刊 | CHEMICAL PHYSICS LETTERS
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ISSN | 0009-2614 |
卷号 | 713页码:105-110 |
摘要 | Kinetics of rubidium extraction by 4-tert-butyl-2-(alpha-methylbenzy) phenol (t-BAMBP)/sulfonated kerosene in brine solutions were investigated using the rising single drop technique. Parameters affecting the mass transfer mechanism, including the interfacial area, initial alkalinity of aqueous phase, concentration of rubidium ions and t-BAMBP, and temperature were studied. The results indicated that the process of extraction was controlled by the diffusion process, while the chemical reaction occurred at the interfacial area. Dynamic equation of the extraction system, R-e= 2.901 x 10(-5) [Rb+](1.022)[OH-](1.179)[t-BAMBP](0.991)was obtained by non-linear fitting the experimental data. Moreover, a new mechanism of the rubidium extraction with t-BAMBP/sulfonated kerosene was proposed. |
DOI | 10.1016/j.cplett.2018.10.021 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/34456 |
专题 | 盐湖资源综合利用工程技术中心 |
推荐引用方式 GB/T 7714 | Huang, Dongfang,Zheng, Hong,Li, Bo,et al. Extraction kinetics of rubidium in brine solutions by 4-tert-butyl-2-(alpha-methylbenzyl)phenol sulfonated kerosene using a single drop method[J]. CHEMICAL PHYSICS LETTERS,2018,713:105-110. |
APA | Huang, Dongfang,Zheng, Hong,Li, Bo,&Ma, Guixiang.(2018).Extraction kinetics of rubidium in brine solutions by 4-tert-butyl-2-(alpha-methylbenzyl)phenol sulfonated kerosene using a single drop method.CHEMICAL PHYSICS LETTERS,713,105-110. |
MLA | Huang, Dongfang,et al."Extraction kinetics of rubidium in brine solutions by 4-tert-butyl-2-(alpha-methylbenzyl)phenol sulfonated kerosene using a single drop method".CHEMICAL PHYSICS LETTERS 713(2018):105-110. |
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