| A quinoline-based chromogenic and ratiometric fluorescent probe for selective detection of Mg2+ ion Design, synthesis and its application in salt lake brines and bioimaging | |
Fu, Zhen-Hai ; Qin, Jing-Can; Wang, Ya-Wen; Peng, Yu; Zhang, Yong-Ming; Zhao, Dong-Mei; Zhang, Zhi-Hong
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| 第一作者 | Fu, Zhen-Hai |
| 2021-02 | |
| 发表期刊 | DYES AND PIGMENTS
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| ISSN | 0143-7208 |
| 卷号 | 185 |
| 摘要 | A fluorescent probe was rational designed and prepared to distinguish Mg2+ ion from Ca2+ ion, in which 8-hydroxyquinoline acted as not only a fluorophore but also a recognition group. Notably, this probe QB (8-hydroxyquinoline-5-benzothiazole) shows two fluorescence response modes for highly selective detection of Mg2+ ion, namely fluorescence ratiometric mode and turn-on mode, which can be realized by controlling the excitation wavelength at 356 nm or 425 nm. After the addition of Mg2+ ion, the color of the QB solution changed from colorless to yellow, which can be easily found by naked eye. All experimental results suggested that probe QB has a high selectivity toward Mg2+ ion in the presence of other cations. Its detection limit for Mg2+ ion was estimated as low as 0.142 mu M, and this value was far lower than the intracellular concentration (0.5-1.2 mM). The detection mechanism was proposed further by the experiment of H-1 NMR titration and theoretical calculation. More significantly, this probe was successfully used to detect Mg2+ ion in brine samples as a quantitative method, and was also applied to detecting and imaging Mg2+ ion in living cells, indicating its great application value in practical use for the detection of Mg2+ ion. |
| DOI | 10.1016/j.dyepig.2020.108896 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.isl.ac.cn/handle/363002/34330 |
| 专题 | 盐湖资源与化学实验室 |
| 推荐引用方式 GB/T 7714 | Fu, Zhen-Hai,Qin, Jing-Can,Wang, Ya-Wen,et al. A quinoline-based chromogenic and ratiometric fluorescent probe for selective detection of Mg2+ ion Design, synthesis and its application in salt lake brines and bioimaging[J]. DYES AND PIGMENTS,2021,185. |
| APA | Fu, Zhen-Hai.,Qin, Jing-Can.,Wang, Ya-Wen.,Peng, Yu.,Zhang, Yong-Ming.,...&Zhang, Zhi-Hong.(2021).A quinoline-based chromogenic and ratiometric fluorescent probe for selective detection of Mg2+ ion Design, synthesis and its application in salt lake brines and bioimaging.DYES AND PIGMENTS,185. |
| MLA | Fu, Zhen-Hai,et al."A quinoline-based chromogenic and ratiometric fluorescent probe for selective detection of Mg2+ ion Design, synthesis and its application in salt lake brines and bioimaging".DYES AND PIGMENTS 185(2021). |
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| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| A quinoline-based ch（8311KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |
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